3rd February 2013
| 5th Round | Dundee | 5-1 | Greenock Morton |
| 5th Round | Raith Rovers | 0-3 | Celtic |
| 5th Round | Hibernian | 1-0 | Aberdeen |
2nd February 2013
| 5th Round | Falkirk | 4-1 | Forfar Athletic |
| 5th Round | St. Mirren | 2-0 | St. Johnstone |
| 5th Round | Kilmarnock | 2-0 |
| 5th Round | Dunfermline Athletic | 0-2 | Hamilton Academical |
| 5th Round | Dundee United | 3-0 | Rangers |
17th December 2012
| 4th Round | Cowdenbeath | 0-3 | St. Johnstone |
| 4th Round | Dumbarton | 1-3 | Hamilton Academical |
| 4th Round Replay | Greenock Morton | 6-0 |
12th December 2012
| 4th Round Replay | Arbroath | 0-1 | Celtic |
11th December 2012
| 4th Round Replay | 2-1 | Ross County |
| 4th Round Replay | Motherwell | 1-2 | Aberdeen |
2nd December 2012
| 4th Round | Hibernian | 1-0 | Heart of Midlothian |
| 4th Round | Rangers | 3-0 | Elgin City |
1st December 2012
| 4th Round | Kilmarnock | 2-1 | Queen of the South |
| 4th Round | Livingston | 0-2 | Dundee |
| 4th Round | Partick Thistle | 0-1 | Dunfermline Athletic |
| 4th Round | Celtic | 1-1 | Arbroath |
| 4th Round | Aberdeen | 1-1 | Motherwell |
| 4th Round | Stranraer | 0-5 | Dundee United |
| 4th Round | 1-1 | Greenock Morton |
| 4th Round | Stenhousemuir | 0-1 | Falkirk |
| 4th Round | Raith Rovers | 2-1 |
| 4th Round | Forfar Athletic | 2-1 | Ayr United |
| 4th Round | Ross County | 3-3 |
| 4th Round | St. Mirren | 2-0 | Brechin City |
13th November 2012
| 3rd Round Replay | Raith Rovers | 4-3 | Airdrie United |
| 3rd Round Replay | Berwick Rangers | 2-5 | Stenhousemuir |
| 3rd Round Replay | Greenock Morton | 3-0 | Albion Rovers |
10th November 2012
| 3rd Round Replay | 0-6 | Brechin City |
| 3rd Round Replay | Arbroath | 3-1 |
| 3rd Round Replay | 2-3 | Forfar Athletic |
| 3rd Round Replay | Queen's Park | 0-4 | Stranraer |
3rd November 2012
| 3rd Round | Cowdenbeath | 8-1 |
| 3rd Round | Dumbarton | 4-1 |
| 3rd Round | Edinburgh City | 0-2 | Queen of the South |
| 3rd Round | Elgin City | 5-1 | East Fife |
| 3rd Round | Forfar Athletic | 3-3 |
| 3rd Round | 3-3 | Arbroath |
| 3rd Round | Partick Thistle | 2-1 |
| 3rd Round | Rangers | 7-0 | Alloa Athletic |
| 3rd Round | Stenhousemuir | 1-1 | Berwick Rangers |
| 3rd Round | Stirling Albion | 0-1 |
| 3rd Round | 0-1 |
| 3rd Round | Brechin City | 2-2 |
| 3rd Round | Stranraer | 1-1 | Queen's Park |
| 3rd Round | Airdrie United | 2-2 | Raith Rovers |
| 3rd Round | Albion Rovers | 1-1 | Greenock Morton |
| 3rd Round | Ayr United | 2-1 |
6th October 2012
| 2nd Round Replay | 3-2 | Clyde |
| 2nd Round Replay | 5-1 |
| 2nd Round Replay | Annan Athletic | 1-2 |
29th September 2012
| 2nd Round | 0-0 | Annan Athletic |
| 2nd Round | Montrose | 1-3 | Edinburgh City |
| 2nd Round | 1-2 |
| 2nd Round | 4-2 |
| 2nd Round | 0-1 | Rangers |
| 2nd Round | 1-2 |
| 2nd Round | 7-0 |
| 2nd Round | Berwick Rangers | 1-0 |
| 2nd Round | 1-1 |
| 2nd Round | 4-3 |
| 2nd Round | 3-2 | Peterhead |
| 2nd Round | Elgin City | 3-1 |
| 2nd Round | 0-5 | Stirling Albion |
| 2nd Round | Queen's Park | 3-0 |
| 2nd Round | Clyde | 3-3 |
| 2nd Round | 0-1 |
1st September 2012
| 1st Round Replay | 0-4 |
| 1st Round Replay | 0-2 |
| 1st Round Replay | Edinburgh City | 4-1 |
25th August 2012
| 1st Round | 0-1 |
| 1st Round | 2-1 |
| 1st Round | 2-2 |
| 1st Round | 1-1 | Edinburgh City |
| 1st Round | 4-0 |
| 1st Round | 1-2 |
| 1st Round | 4-0 |
| 1st Round | 0-2 |
| 1st Round | 2-1 |
| 1st Round | 2-4 |
| 1st Round | 6-1 |
| 1st Round | 1-4 |
| 1st Round | 0-2 |
| 1st Round | 3-2 |
| 1st Round | 0-0 |
| 1st Round | 2-4 |
| 1st Round | 4-0 |
| 1st Round | 0-2 |
4th August 2012
| Preliminary Round | 1-3 |
| Preliminary Round | 0-1 |