2000-2014 Copyright Digital Sports Group LTD, All Rights Reserved
3rd February 2013
| 5th Round | Hibernian | 1-0 | Aberdeen |
| 5th Round | Raith Rovers | 0-3 | Celtic |
| 5th Round | Dundee | 5-1 | Greenock Morton |
2nd February 2013
| 5th Round | St. Mirren | 2-0 | St. Johnstone |
| 5th Round | Falkirk | 4-1 | Forfar Athletic |
| 5th Round | Kilmarnock | 2-0 | Inverness Caledonian Thistle |
| 5th Round | Dundee United | 3-0 | Rangers |
| 5th Round | Dunfermline Athletic | 0-2 | Hamilton Academical |
17th December 2012
| 4th Round Replay | Greenock Morton | 6-0 | Turriff United |
| 4th Round | Dumbarton | 1-3 | Hamilton Academical |
| 4th Round | Cowdenbeath | 0-3 | St. Johnstone |
12th December 2012
| 4th Round Replay | Arbroath | 0-1 | Celtic |
11th December 2012
| 4th Round Replay | Inverness Caledonian Thistle | 2-1 | Ross County |
| 4th Round Replay | Motherwell | 1-2 | Aberdeen |
2nd December 2012
| 4th Round | Hibernian | 1-0 | Heart of Midlothian |
| 4th Round | Rangers | 3-0 | Elgin City |
1st December 2012
| 4th Round | Turriff United | 1-1 | Greenock Morton |
| 4th Round | Ross County | 3-3 | Inverness Caledonian Thistle |
| 4th Round | Celtic | 1-1 | Arbroath |
| 4th Round | Forfar Athletic | 2-1 | Ayr United |
| 4th Round | Partick Thistle | 0-1 | Dunfermline Athletic |
| 4th Round | St. Mirren | 2-0 | Brechin City |
| 4th Round | Aberdeen | 1-1 | Motherwell |
| 4th Round | Stenhousemuir | 0-1 | Falkirk |
| 4th Round | Stranraer | 0-5 | Dundee United |
| 4th Round | Livingston | 0-2 | Dundee |
| 4th Round | Raith Rovers | 2-1 | Deveronvale |
| 4th Round | Kilmarnock | 2-1 | Queen of the South |
13th November 2012
| 3rd Round Replay | Berwick Rangers | 2-5 | Stenhousemuir |
| 3rd Round Replay | Greenock Morton | 3-0 | Albion Rovers |
| 3rd Round Replay | Raith Rovers | 4-3 | Airdrie United |
10th November 2012
| 3rd Round Replay | Queen's Park | 0-4 | Stranraer |
| 3rd Round Replay | Arbroath | 3-1 | Inverurie Loco Works |
| 3rd Round Replay | Nairn County | 2-3 | Forfar Athletic |
| 3rd Round Replay | Bonnyrigg Rose | 0-6 | Brechin City |
3rd November 2012
| 3rd Round | Albion Rovers | 1-1 | Greenock Morton |
| 3rd Round | Partick Thistle | 2-1 | Cove Rangers |
| 3rd Round | Stirling Albion | 0-1 | Deveronvale |
| 3rd Round | Inverurie Loco Works | 3-3 | Arbroath |
| 3rd Round | Stenhousemuir | 1-1 | Berwick Rangers |
| 3rd Round | Elgin City | 5-1 | East Fife |
| 3rd Round | Dumbarton | 4-1 | East Stirlingshire |
| 3rd Round | Forfar Athletic | 3-3 | Nairn County |
| 3rd Round | Airdrie United | 2-2 | Raith Rovers |
| 3rd Round | Stranraer | 1-1 | Queen's Park |
| 3rd Round | Cowdenbeath | 8-1 | Vale of Leithen |
| 3rd Round | Edinburgh City | 0-2 | Queen of the South |
| 3rd Round | Brechin City | 2-2 | Bonnyrigg Rose |
| 3rd Round | Buckie Thistle | 0-1 | Turriff United |
| 3rd Round | Rangers | 7-0 | Alloa Athletic |
| 3rd Round | Ayr United | 2-1 | Clachnacuddin |
6th October 2012
| 2nd Round Replay | Vale of Leithen | 5-1 | Selkirk |
| 2nd Round Replay | Annan Athletic | 1-2 | Buckie Thistle |
| 2nd Round Replay | Nairn County | 3-2 | Clyde |
29th September 2012
| 2nd Round | Deveronvale | 3-2 | Peterhead |
| 2nd Round | Clyde | 3-3 | Nairn County |
| 2nd Round | Selkirk | 1-1 | Vale of Leithen |
| 2nd Round | Elgin City | 3-1 | St. Cuthbert Wanderers |
| 2nd Round | Queen's Park | 3-0 | Irvine Meadow |
| 2nd Round | Montrose | 1-3 | Edinburgh City |
| 2nd Round | Cove Rangers | 7-0 | Golspie Sutherland |
| 2nd Round | Berwick Rangers | 1-0 | Wick Academy |
| 2nd Round | Fraserburgh | 1-2 | East Stirlingshire |
| 2nd Round | Buckie Thistle | 0-0 | Annan Athletic |
| 2nd Round | Forres Mechanics | 0-1 | Rangers |
| 2nd Round | Civil Service Strollers | 1-2 | Turriff United |
| 2nd Round | Dalbeattie Star | 0-5 | Stirling Albion |
| 2nd Round | Clachnacuddin | 4-2 | Formartine United |
| 2nd Round | Inverurie Loco Works | 4-3 | Huntly |
| 2nd Round | Stirling University | 0-1 | Bonnyrigg Rose |
1st September 2012
| 1st Round Replay | Wigtown & Bladnoch | 0-2 | Huntly |
| 1st Round Replay | Edinburgh City | 4-1 | Shotts Bon Accord |
| 1st Round Replay | Rothes | 0-4 | Buckie Thistle |
25th August 2012
| 1st Round | Huntly | 2-2 | Wigtown & Bladnoch |
| 1st Round | Hawick Royal Albert | 2-4 | Golspie Sutherland |
| 1st Round | Civil Service Strollers | 4-0 | Newton Stewart |
| 1st Round | Edinburgh University | 1-2 | St. Cuthbert Wanderers |
| 1st Round | Shotts Bon Accord | 1-1 | Edinburgh City |
| 1st Round | Formartine United | 3-2 | Brora Rangers |
| 1st Round | Irvine Meadow | 4-0 | Gala Fairydean |
| 1st Round | Whitehill Welfare | 2-4 | Inverurie Loco Works |
| 1st Round | Preston Athletic | 0-2 | Nairn County |
| 1st Round | Fraserburgh | 4-0 | Coldstream |
| 1st Round | Buckie Thistle | 0-0 | Rothes |
| 1st Round | Glasgow University | 0-2 | Selkirk |
| 1st Round | Clachnacuddin | 2-1 | Lossiemouth |
| 1st Round | Threave Rovers | 0-1 | Vale of Leithen |
| 1st Round | Bonnyrigg Rose | 2-1 | Girvan |
| 1st Round | Spartans | 0-2 | Wick Academy |
| 1st Round | Turriff United | 6-1 | Burntisland Shipyard |
| 1st Round | Hermes | 1-4 | Deveronvale |
4th August 2012
| Preliminary Round | Fort William | 1-3 | Preston Athletic |
| Preliminary Round | Keith | 0-1 | St. Cuthbert Wanderers |
2000-2014 Copyright Digital Sports Group LTD, All Rights Reserved