19th May 2012
| Final | Hibernian | 1-5 | Heart of Midlothian |
15th April 2012
| Semi Final | Celtic | 1-2 | Heart of Midlothian |
14th April 2012
| Semi Final | Aberdeen | 1-2 | Hibernian |
21st March 2012
| Quarter Final Replay | St. Mirren | 0-2 | Heart of Midlothian |
11th March 2012
| Quarter Final | Motherwell | 1-2 | Aberdeen |
| Quarter Final | Dundee United | 0-4 | Celtic |
10th March 2012
| Quarter Final | Ayr United | 0-2 | Hibernian |
| Quarter Final | Heart of Midlothian | 2-2 | St. Mirren |
15th February 2012
| 5th Round | Ayr United | 2-1 | Falkirk |
14th February 2012
| 5th Round Replay | St. Johnstone | 1-2 | Heart of Midlothian |
| 5th Round Replay | Ross County | 1-2 | St. Mirren |
| 5th Round Replay | Queen of the South | 1-2 | Aberdeen |
5th February 2012
| 5th Round | Heart of Midlothian | 1-1 | St. Johnstone |
| 5th Round | Rangers | 0-2 | Dundee United |
4th February 2012
| 5th Round | St. Mirren | 1-1 | Ross County |
| 5th Round | Motherwell | 6-0 | Greenock Morton |
| 5th Round | Hibernian | 1-0 | Kilmarnock |
| 5th Round | Aberdeen | 1-1 | Queen of the South |
| 5th Round | Inverness Caledonian Thistle | 0-2 | Celtic |
18th January 2012
| 4th Round Replay | Dunfermline Athletic | 1-3 | Inverness Caledonian Thistle |
17th January 2012
| 4th Round Replay | 0-1 | St. Mirren |
| 4th Round Replay | Kilmarnock | 2-1 | Dundee |
8th January 2012
| 4th Round | Peterhead | 0-3 | Celtic |
| 4th Round | Arbroath | 0-4 | Rangers |
7th January 2012
| 4th Round | Motherwell | 4-0 | Queen's Park |
| 4th Round | Falkirk | 2-0 | East Fife |
| 4th Round | Inverness Caledonian Thistle | 1-1 | Dunfermline Athletic |
| 4th Round | Partick Thistle | 0-1 | Queen of the South |
| 4th Round | Forfar Athletic | 0-4 | Aberdeen |
| 4th Round | St. Johnstone | 2-1 | Brechin City |
| 4th Round | Cowdenbeath | 2-3 | Hibernian |
| 4th Round | Heart of Midlothian | 1-0 |
| 4th Round | Livingston | 1-2 | Ayr United |
| 4th Round | Ross County | 7-0 | Stenhousemuir |
| 4th Round | Raith Rovers | 1-2 | Greenock Morton |
| 4th Round | Dundee | 1-1 | Kilmarnock |
| 4th Round | St. Mirren | 0-0 |
| 4th Round | Airdrie United | 2-6 | Dundee United |
26th November 2011
| 3rd Round Replay | Queen's Park | 3-1 | Elgin City |
| 3rd Round Replay | Partick Thistle | 4-0 |
| 3rd Round Replay | Forfar Athletic | 3-0 | Stranraer |
22nd November 2011
| 3rd Round Replay | Montrose | 1-2 | Ayr United |
19th November 2011
| 3rd Round | Elgin City | 1-1 | Queen's Park |
| 3rd Round | Airdrie United | 11-0 |
| 3rd Round | 0-6 | Livingston |
| 3rd Round | Ross County | 4-0 | Albion Rovers |
| 3rd Round | 0-1 | Arbroath |
| 3rd Round | 2-4 | Peterhead |
| 3rd Round | Brechin City | 3-0 | Dumbarton |
| 3rd Round | 0-3 | Cowdenbeath |
| 3rd Round | 1-1 | Partick Thistle |
| 3rd Round | Stenhousemuir | 4-0 | Annan Athletic |
| 3rd Round | Stirling Albion | 1-2 | Dundee |
| 3rd Round | Stranraer | 1-1 | Forfar Athletic |
| 3rd Round | East Fife | 5-0 |
| 3rd Round | Greenock Morton | 5-1 |
| 3rd Round | 3-1 |
| 3rd Round | Ayr United | 2-2 | Montrose |
29th October 2011
| 2nd Round Replay | Annan Athletic | 2-0 | Alloa Athletic |
| 2nd Round Replay | 2-4 |
| 2nd Round Replay | Elgin City | 5-2 |
| 2nd Round Replay | 3-2 |
23rd October 2011
| 2nd Round | 1-1 |
22nd October 2011
| 2nd Round | Montrose | 2-1 | Clyde |
| 2nd Round | 0-3 | Queen's Park |
| 2nd Round | 8-1 |
| 2nd Round | 4-0 |
| 2nd Round | Alloa Athletic | 2-2 | Annan Athletic |
| 2nd Round | 0-2 |
| 2nd Round | 0-1 |
| 2nd Round | Peterhead | 2-0 |
| 2nd Round | 0-9 | Stranraer |
| 2nd Round | 0-0 | Elgin City |
| 2nd Round | 2-1 |
| 2nd Round | 5-2 |
| 2nd Round | 3-2 | Cove Rangers |
| 2nd Round | 1-1 |
| 2nd Round | Edinburgh City | 0-1 |
1st October 2011
| 1st Round | 0-4 |
| 1st Round Replay | 6-3 |
24th September 2011
| 1st Round | 1-0 |
| 1st Round | 0-4 | Cove Rangers |
| 1st Round | 9-1 |
| 1st Round | 1-6 |
| 1st Round | 2-2 |
| 1st Round | 0-3 |
| 1st Round | 6-1 |
| 1st Round | 1-2 |
| 1st Round | 2-0 |
| 1st Round | 4-3 |
| 1st Round | 2-1 |
| 1st Round | Edinburgh City | 3-0 |
| 1st Round | 8-1 |
| 1st Round | 0-3 |
| 1st Round | 0-2 |
| 1st Round | 4-0 |