18th February 2014
| 5th Round Replay | 2-0 |
9th February 2014
| 5th Round | Dundee United | 2-1 | St. Mirren |
8th February 2014
| 5th Round | 2-2 |
| 5th Round | Hibernian | 2-3 |
| 5th Round | 0-4 |
| 5th Round | 0-1 |
| 5th Round | 2-0 |
| 5th Round | Celtic | 1-2 | Aberdeen |
10th December 2013
| 4th Round Replay | 3-3 |
| 4th Round Replay | St. Mirren | 3-0 |
| 4th Round Replay | 4-1 |
4th December 2013
| 4th Round Replay | 1-0 |
1st December 2013
| 4th Round | 0-1 | Aberdeen |
| 4th Round | Heart of Midlothian | 0-7 | Celtic |
30th November 2013
| 4th Round | 1-1 |
| 4th Round | 1-1 |
| 4th Round | 0-1 | Hibernian |
| 4th Round | 2-2 | St. Mirren |
| 4th Round | 3-0 |
| 4th Round | 0-1 |
| 4th Round | 2-0 | Livingston |
| 4th Round | 4-0 |
| 4th Round | 0-2 | Rangers |
| 4th Round | 1-3 |
| 4th Round | 1-0 | Motherwell |
| 4th Round | 3-2 |
29th November 2013
| 4th Round | Dundee United | 5-2 | Kilmarnock |
12th November 2013
| 3rd Round Replay | 2-4 |
9th November 2013
| 3rd Round | 2-3 |
| 3rd Round | 3-1 |
3rd November 2013
| 3rd Round | 0-2 |
2nd November 2013
| 3rd Round | 1-0 |
| 3rd Round | 2-1 |
| 3rd Round | 1-0 |
| 3rd Round | 0-2 |
| 3rd Round | 2-2 |
| 3rd Round | 2-1 |
| 3rd Round | 0-3 |
1st November 2013
| 3rd Round | Rangers | 3-0 |
19th October 2013
| 2nd Round Replay | 4-0 |
12th October 2013
| 2nd Round Replay | 2-0 |
| 2nd Round Replay | 0-3 |
| 2nd Round Replay | 1-2 |
| 2nd Round Replay | 1-2 |
| 2nd Round Replay | 1-3 |
6th October 2013
| 2nd Round | 6-0 |
5th October 2013
| 2nd Round | 1-1 |
| 2nd Round | 0-1 |
| 2nd Round | 4-4 |
| 2nd Round | 2-1 |
| 2nd Round | 0-4 |
| 2nd Round | 2-2 |
| 2nd Round | 4-0 |
| 2nd Round | 0-2 |
| 2nd Round | 0-0 |
| 2nd Round | 2-2 |
| 2nd Round | 0-6 |
| 2nd Round | 2-2 |
| 2nd Round | 0-3 |
| 2nd Round | 4-2 |
| 2nd Round | 1-0 |
21st September 2013
| 1st Round Replay | 3-1 |
| 1st Round Replay | 3-1 |
14th September 2013
| 1st Round | 2-0 |
| 1st Round | 0-2 |
| 1st Round | 3-0 |
| 1st Round | 0-4 |
| 1st Round | 3-4 |
| 1st Round | 0-6 |
| 1st Round | 1-5 |
| 1st Round | 3-0 |
| 1st Round | 1-3 |
| 1st Round | 0-0 |
| 1st Round | 4-5 |
| 1st Round | 4-0 |
| 1st Round | 3-1 |
| 1st Round | 3-4 |
| 1st Round | 1-0 |
| 1st Round | 5-0 |
| 1st Round | 0-1 |
| 1st Round | 0-0 |