17th March 2013
| Final | Heart of Midlothian | 3-2 | St. Mirren |
27th January 2013
| Semi Final | St. Mirren | 3-2 | Celtic |
26th January 2013
| Semi Final | Inverness Caledonian Thistle | 1-1 | Heart of Midlothian |
31st October 2012
| Quarter Final | Rangers | 0-3 | Inverness Caledonian Thistle |
| Quarter Final | Dundee United | 1-1 | Heart of Midlothian |
30th October 2012
| Quarter Final | Aberdeen | 2-2 | St. Mirren |
| Quarter Final | Celtic | 5-0 | St. Johnstone |
26th September 2012
| 3rd Round | Rangers | 2-0 | Motherwell |
| 3rd Round | Dunfermline Athletic | 0-1 | Aberdeen |
25th September 2012
| 3rd Round | Celtic | 4-1 | Raith Rovers |
| 3rd Round | St. Mirren | 1-0 | Hamilton Academical |
| 3rd Round | Queen of the South | 0-1 | Dundee United |
| 3rd Round | Heart of Midlothian | 3-1 | Livingston |
| 3rd Round | St. Johnstone | 4-1 | Queen's Park |
| 3rd Round | Stenhousemuir | 1-1 | Inverness Caledonian Thistle |
30th August 2012
| 2nd Round | Rangers | 3-0 | Falkirk |
29th August 2012
| 2nd Round | St. Mirren | 5-1 | Ayr United |
| 2nd Round | Queen's Park | 2-1 | Dundee |
| 2nd Round | Arbroath | 0-2 | Inverness Caledonian Thistle |
28th August 2012
| 2nd Round | Dunfermline Athletic | 3-0 | Montrose |
| 2nd Round | Queen of the South | 2-0 | Hibernian |
| 2nd Round | Kilmarnock | 1-2 | Stenhousemuir |
| 2nd Round | Hamilton Academical | 1-0 | Partick Thistle |
| 2nd Round | 1-4 | Raith Rovers |
| 2nd Round | Livingston | 3-2 | Dumbarton |
22nd August 2012
| 2nd Round | Greenock Morton | 0-2 | Aberdeen |
7th August 2012
| 1st Round | Rangers | 4-0 | East Fife |
5th August 2012
| 1st Round | 1-5 | Greenock Morton |
4th August 2012
| 1st Round | Montrose | 2-1 | Cowdenbeath |
| 1st Round | Stenhousemuir | 4-0 | Brechin City |
| 1st Round | Raith Rovers | 4-3 |
| 1st Round | Stranraer | 0-8 | Livingston |
| 1st Round | Queen of the South | 5-2 | Alloa Athletic |
| 1st Round | Ayr United | 6-1 | Clyde |
| 1st Round | Queen's Park | 3-2 | Airdrie United |
| 1st Round | Dumbarton | 2-0 | Albion Rovers |
| 1st Round | Forfar Athletic | 0-2 | Partick Thistle |
| 1st Round | Hamilton Academical | 2-0 | Annan Athletic |
| 1st Round | Arbroath | 1-1 | Stirling Albion |
| 1st Round | Falkirk | 2-0 | Elgin City |
31st July 2012
| 1st Round | Peterhead | 0-0 | Dundee |