18th March 2007
| Final | Kilmarnock | 1-5 | Hibernian |
31st January 2007
| Semi Final | Hibernian | 3-1 | St. Johnstone |
30th January 2007
| Semi Final | Falkirk | 0-3 | Kilmarnock |
8th November 2006
| Quarter Final | Rangers | 0-2 | St. Johnstone |
| Quarter Final | Hibernian | 1-0 | Heart of Midlothian |
7th November 2006
| Quarter Final | Celtic | 1-1 | Falkirk |
| Quarter Final | Kilmarnock | 3-2 | Motherwell |
20th September 2006
| 3rd Round | Alloa Athletic | 0-4 | Heart of Midlothian |
| 3rd Round | Dunfermline Athletic | 0-2 | Rangers |
| 3rd Round | Queen's Park | 0-3 | Motherwell |
| 3rd Round | Hibernian | 6-0 |
19th September 2006
| 3rd Round | Celtic | 2-0 | St. Mirren |
| 3rd Round | Kilmarnock | 2-1 | Livingston |
| 3rd Round | St. Johnstone | 3-0 | Dundee United |
| 3rd Round | Inverness Caledonian Thistle | 0-1 | Falkirk |
23rd August 2006
| 2nd Round | Inverness Caledonian Thistle | 3-1 | Dumbarton |
22nd August 2006
| 2nd Round | Ayr United | 0-0 | Dunfermline Athletic |
| 2nd Round | Brechin City | 0-3 | Livingston |
| 2nd Round | Cowdenbeath | 0-5 | Falkirk |
| 2nd Round | Dundee United | 1-0 | Airdrie United |
| 2nd Round | Hibernian | 4-0 | Peterhead |
| 2nd Round | Motherwell | 3-2 | Partick Thistle |
| 2nd Round | Queen of the South | 1-2 | Kilmarnock |
| 2nd Round | Queen's Park | 0-0 | Aberdeen |
| 2nd Round | St. Johnstone | 4-0 | Elgin City |
| 2nd Round | St. Mirren | 3-1 | Stenhousemuir |
| 2nd Round | Alloa Athletic | 2-1 | Ross County |
9th August 2006
| 1st Round | Arbroath | 0-1 | Elgin City |
| 1st Round | Montrose | 1-3 | Peterhead |
| 1st Round | Ayr United | 2-0 |
8th August 2006
| 1st Round | Forfar Athletic | 1-2 | Alloa Athletic |
| 1st Round | Dumbarton | 3-0 | Stirling Albion |
| 1st Round | Raith Rovers | 1-2 | Airdrie United |
| 1st Round | Queen's Park | 2-1 |
| 1st Round | Queen of the South | 4-2 | Clyde |
| 1st Round | Ross County | 4-2 | Stranraer |
| 1st Round | Dundee | 1-3 | Partick Thistle |
| 1st Round | Cowdenbeath | 4-1 |
| 1st Round | Brechin City | 2-1 | Greenock Morton |
| 1st Round | Albion Rovers | 1-2 | Stenhousemuir |
| 1st Round | St. Johnstone | 3-1 | East Fife |